May 9, 2014 - with the measurement of actual thermal conductivity of pipe insulation systems with moisture ingress, and future research needs in this area are discussed. ... design pipe insulation systems with the aim of preventing such condensation.
resistance of 1 Â°C/W, the total resistance is 2 Â°C/W. A common engineering design problem involves the selection of an appropriate sized heat sink for a given heat source. Working in units of thermal resistance greatly simplifies the design calcula
May 13, 2015 - cases, respectively. Our numerical method quantifies the role of electronic band structure and carrier scattering mechanisms. We have successfully demonstrated bipolar thermal conductivity reduction in doped semiconductors via electron
average of at least six measurements generally from between measurements five and ten. The average thermal conductivity values reported for each sample have typical standard devia- tions from 0.01 to 0.30 W mÐ1 KÐ1, with most less than. 0.10 W mÐ1
Jan 15, 2009 - Rawat, Vijay; Koh, Yee Kan; Cahill, David G.; and Sands, Timothy D., "Thermal conductivity of (Zr,W)N/ScN metal/semiconductor ... to the lattice component of the thermal conductivity of a Zr0.65Sc0.35N alloy film (5 W/m K). Alloying th
Measurement of thermal conductivity. Part A: P t Bar : â¢ Time domain ... thermal conductance from sidewalls to ambient. Modern application to suspended ... Schmidt et al., RSI 2008. â¢ Heat supplied by modulated pump beam (fundamental. Fourier com
Department of Electrical Apparatus and Switchgear. Gustav-Kirchhoff-Strasse 1, 98693 ... For this purpose, step response measurements in time domain are performed with a sensitive current device. Furthermore, the influence of ... rent (AC) from grid
between predictions from molecular dynamics simulations (a method valid at temperatures above the Debye temperature) ... A key feature of ionic materials is the presence of the long-range electrostatic interactions whose influence ... ranged and repr
Closer look at. â« Vapour Permeability and its effect on insulation materials. â« Test conditions versus actual operation conditions. â« Detailed comparisons of insulation materials. â« Thermal conductivity of various insulation materials. â« Th
Sep 15, 1972 - values of high temperature gases is evident, all but a in their long (8 ft) and narrow (1.22-in. diam) test ..... Eqs. (4) and (5) yield. (6). TABLE I. Estimate of random errors (percent). Temp. range. Temp. 800-1200 1200-1600 1600-200
May 2, 2011 - Qavg=50 mW, and has Tavg=7.6 K. Caution should be taken to minimize Tavg for low thermal conductivity samples by using low pump laser power or low duty-cycle periodic modulation that result in low Qavg. For the room temperature validati
Dec 31, 2016 - oils) are usually used as heat transfer fluids: in thermal engines (coolants ... alumina/water and copper oxide/water nanofluids are performed and ... Thus, we try in this work to answer the following fundamental ... In this case, the
Abstract. In recent years, many studies have been conducted regarding polymer nanocomposites, namely polymers doped with various forms of graphene. The impact toughness, tensile strength, and thermal conductivity of Polypropylene/ Graphene and. Polys
(MD) simulations with realistic anharmonic potentials and to experimental measurements. The harmonic theory accurately predicts the thermal conductivity of amorphous-silicon, a model. Lennard-Jones glass, and a bead-spring Lennard-Jones glass. For po
Nov 4, 2015 - range spanning 24 Â°C to 80 Â°C. The thermal conductivity of the Ag-DNTT hybrid thin film initially decreases and then increases when the Ag ...
Feb 19, 2016 - To date, there is no experimental characterization of thermal conductivity of semiconductor polymeric individual nanowires embedded in a matrix. This work reports on scanning thermal microscopy measurements in a 3u configuration to det
clothing area factors (Æcl) determined in two different ways were compared. The first ... covers most of the male body (86%) except for the hands, head and feet. The ..... cotton. 0.213. 26. Hijab. 12% polyester. 0.062. 23. Pants. 15% cotton. 0.028.
Dec 14, 2010 - This thesis, âIn-Plane Thermal Conductivity Modeling of Carbon Filled Liquid. Crystal Polymer Based Resins,â is hereby approved in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE in the field of Chemical
Big picture goals of our work: â Understand and push the limits of thermal conductivity in various classes of materials. â enhance thermal function in materials, e.g., abrupt changes in conductivity, actively controlled conduction, more efficient
May 4, 2016 - for thermal measurements was fabricated by dry-transfer method, whose sample quality, due to less polymer residues ... A PMMA-free technique was used to fabricate suspended ... 1Center for Phononics and Thermal Energy Science, School of
NANOFLUID THERMAL CONDUCTIVITY-A REVIEW. Ravi Sankar.B. 1. , Nageswara Rao. D. 2. ,Srinivasa Rao.Ch. 3. 1. Lecturer, Mechanical Engg. Deptt., R.V.R&J.C. College of Engg., Guntur, A.P, India. 2. Vice-Chancellor, Centurion University, Odisa, India. 3.
Oct 21, 2016 - host lattice of MoS2 undergoes a phase transition from 2H to 1T phase19. The voltage dip at the initial stage of the discharge curve for bulk MoS2 sample is caused by the mass transport limitation of lithium ions. The voltage gradually
applications ranging from microelectronic devices to energy storage and energy conversion devices. Here, we report ultralow lattice thermal conductivities of solution-synthesized, single- crystalline all-inorganic halide perovskite nanowires composed
Eleventh International IBPSA Conference Glasgow, Scotland July 27-30, 2009
UNCERTAINTY IN THE THERMAL CONDUCTIVITY OF INSULATION MATERIALS F. Domínguez-Muñoz1, B.Anderson2, J.M. Cejudo-López1, A. Carrillo-Andrés1 1 Dpto. de Máquinas y Motores Térmicos, Grupo de Energética, Universidad de Málaga Plaza El Ejido s/n, 29013 Málaga (Spain), e-mail: [email protected] 2 BRE Scotland. Orion House, Scottish Enterprise Technology Park, East Kilbridge, Glasgow G75 0RD (Scotland, UK)
transparency to thermal radiation or type and pressure of the gas come into play (ASHRAE, 2005).
Increasing attention is being paid to the application of uncertainty and sensitivity analysis methods to model validation and building simulation. The idea is to let users to apply uncertainty bands to their model input data. These bands are then propagated through the model to determine the uncertainty bands of the simulation results. Mathematical methods to deal with uncertainties in computer simulations are well developed. One of the main difficulties the practitioner finds when trying to apply these techniques to building simulation is the lack of information on the uncertainty that affects to typical input variables (thermophysical properties of materials, internal gains, infiltration, etc.). This paper is a contribution to fill this gap. We present polynomial fits for the average thermal conductivity and its standard deviation as functions of density for typical insulation materials. These functions were obtained by processing a large experimental data set, which was compiled in a previous European project headed by the BRE Scottish Laboratory. To illustrate how these results can be used in practice, an example is discussed on the validation of the mathematical model of a solar thermal collector.
For a given aged material sample, the average conductivity mainly depends on density (ρ), temperature (T) and water content (w, when the material is hygroscopic). However, these three factors do not fully explain the value of conductivity, and dispersion remains due to differences in raw material properties, manufacturing process, etc. Conductivity can then be written as an average value ( k ) plus a random deviation (δ): k = f ( ρ , T , w; other factors) = k ( ρ , T , w) + δ
INTRODUCTION Insulation materials are extensively used to reduce the heat losses (or gains) from thermal systems like buildings, pipes and ducts, components of HVAC installations, etc. In these systems, the insulation layers account for most of the thermal resistance between the hot (or cold) element/s and the environment. Most mass-type thermal insulation materials are highly porous, and consist of a solid matrix full of small voids that comprise 90% or more of the total volume. These voids contain air or some other harmless gas such as CO2. The apparent conductivity of the material is the macroscopic result of various basic heat transfer mechanisms: solid and gas conduction, gas convection and long-wave radiation within the voids. From the macroscopic point of view, the apparent conductivity mainly depends on the kind of insulation, bulk density, temperature, water content, thickness and age. From the microscopic point of view, factors such as cell size, diameter and arrangement of fibres or particles,
For example, figure 1 shows a set of 1340 measurements for the conductivity of expanded polystyrene (EPS) at 10ºC, and dry and aged material. The key independent variable is density. Dispersion around the average conductivity is clearly seen in this figure.
Thermal conductivity [W·m-1·K-1]
Experimental data Average value Upper limit
Temperature = 10ºC Dry, aged material
-3 Density [kg·m ]
Figure 1 Measurements for EPS Standard methods like the calibrated hotbox or the guarded hotbox (EN 12939, 2001) are the best procedures to determine the exact conductivity of a specific material sample. However, practical constrains often lead to use tabulated values. Wellknown and widely used sources of thermo-physical properties are (ASHRAE, 2005), (CIBSE, 2006), (EN12524, 2000), (ISO10456, 2001) and (EN1745, 2002). These references always provide design (“worst-case” or “safe”) values. In figure 1, this idea would correspond to the “upper limit” dashed curve, which normally stands for the 90% fractile.
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an optimistic uncertainty.
While design values are adequate for the majority of the simulation works, there are at least two situations in which practitioners need full information on how the conductivity spreads around the average: (a) validation studies, (b) building simulation under uncertainty. In both cases, inputs to the model are often described as probability distributions, and Monte Carlo simulations are performed to propagate these uncertainties to the result/s. Three examples of validation papers that require data on dispersion are (Strachan, 1993), (Palomo et al., 2003) and (Dominguez et al., 2008). Building simulation under uncertainty is a relatively new branch of building physics. Some of the pioneer works were (Lomas et al., 1992), (MacDonald, 2001) and (deWit, 2001).
The “Thermal Values Group” (Anderson et al., 1999) collected a more comprehensive set of measurements in preparation of a new generation of European Standards on thermal properties; see, for example (EN 12524, 2000), (ISO 10456, 2001) and (EN1745, 2002). This working group consisted of seven national European laboratories that compiled hundreds of measurements of conductivity of different materials. Samples from several European manufactures were tested.
In this paper, we provide explicit expressions for the average conductivity and its standard deviation for common insulation materials. To accomplish this task, the first problem we faced was to find enough quality-controlled measurements of conductivity for different densities and materials. Section 1 reviews the available data sources and describes the data set that has been used in this paper. Section 2 describes the fitting method applied on the raw measurements to derive the polynomial fitting equations. Section 3 presents the main results of the paper, the fitting coefficients. Section 4 is devoted to a case study that shows how the results of Section 3 can be used to validate the model of a thermal flat-plate solar collector. Section 5 presents the general conclusions and discusses further lines of research.
⎡⎣ ρ , k (10º C , dry, aged )⎤⎦ n pairs
This paper is based on the measurements collected by the Thermal Values Group for insulation materials. The format of the available data will now be briefly described. As conductivity depends on temperature, water content and age, all measurements were referenced to standard conditions, in particular to “declared conditions I(a)” as defined in (ISO 10456, 2001): average temperature 10ºC, dry and aged material. The raw data has the following format:
where n is the number of available data points and ρ is the bulk density. Table 1 lists the materials considered in this paper and the number of measurements available for each of them. Table 1 Available data
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
Standard sources of thermo-physical properties have limitations that make it difficult to extract average values and standard deviations. To quantify the intrinsic uncertainty in the thermal conductivity of a material, a large and representative number of measurements is needed. In this section, we describe two data sources that are well suited for such a purpose. The report (Clarke et al., 1990) has been the most extensive and best-known compilation of thermophysical properties of building materials for many years. It contains data from 14 international sources. This information was used in (MacDonald, 2001) to propose uncertainties for different material classes. However, the authors of the report identified some issues that limit the applicability of the data set that they provide:
The sources of much of the data are not identified, and little information is given on the underlying experimental conditions or procedure, and on properties such as density and internal structure Much of the agreement that does exist between different sources may be attributable to historical ‘borrowing’ one from the other. This may lead to
Material Expanded polystyrene (EPS) Extruded polystyrene (XPS) CO2 Polyurethane with pentane Foil-faced polyurethane pentane Polyurethane with CO2 Polyester fibre Phenolic foam Mineral wool (rock), flow ⊥ fibre Mineral wool (glass) Cellular glass / foam glass Wood chip board Wood fibre board Wood wool board Sheep’s wool Cotton Expanded cork Expanded perlite board Cellulose fibre (loose-fill)
METHODOLOGY In (Anderson et al., 1999), data set (2) was processed to calculate the 50% and 90% fractiles of the conductivity of each material at different densities. The 90% fractiles are commonly used in heat transfer calculations. For example, they are used in the new
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Spanish energy standard and in its calculation tool (CTE, 2007). In the present paper, data set (2) was processed to fit equations for the average conductivity and its standard deviation (uncertainty band):
σ = g ( ρ ; T = 10º C , w 0, aged )
Raw data, glass wool Average Limits, WLSQ Limits, OLSQ
k = f ( ρ ; T = 10º C , w 0, aged )
It is important to remark that tables 2 and 3 give the conductivity at declared conditions I(a). Conversion from declared conditions to another set of conditions can be carried out accordingly to the method explained in (ISO 10456, 1999).
Assuming a normally distributed deviation, the true value of the conductivity of any sample would lie within the interval [ k ± 2σ] with a 95.5% probability, and within [ k ± 3σ] with a 99.7% probability.
Declared conditions, I(a)
After testing several regression models, materials in table 1 were divided into two categories. The first group comprises materials 2, 3, 4, 5 and 7. These materials do not show a clear dependency between conductivity and density within the considered density range, so functions f in (3) and g in (4) reduce to constant values. For the rest of materials, the following simple regression model fits well the averages: k = a + b ρ + c ρ −1
Parameters a, b and c are usually estimated by the ordinary least squares method OLSQ, see (Press, 1992). This method assumes a constant standard deviation, so equation (4) reduces to:
σ = d = constant
Figure 2 Weighted vs. ordinary least squares fit
CASE STUDY This case study illustrates how data from table 2 can be used in a model validation exercise. The aim is to validate the well known Hottel-Whillier flat plate solar collector model; see (Duffie et al., 2006) and (Koo, 1999) for details. Figure 3 depicts the basic elements of a sheet-andtube solar collector. The following discussion will focus on the back insulation layer. The complete validation study can be found in (Dominguez et al., 2008).
However, a close examination of the residuals of the regression models shows that materials 1, 9, 15 and 18 exhibit a significant relationship between the standard deviation of conductivity (σ, dependent variable) and density (ρ, independent variable). This property of the data is called heteroscedasticity. In these cases, standard deviation was fitted by another polynomial function:
σ = d + e ρ + f ρ −1
Coefficients in equations (5) and (7) were estimated by the weighted least squares method WLSQ, see (NIST, 2006) and (STATSOFT, 2009). Figure 2 is an example on how the WLSQ method improves the results when compared to the OLSQ method. WLSQ-calculated uncertainty bands (dashed lines in figure 2) more closely resemble the measured data, whose deviation decreases with density.
RESULTS Table 2 shows the coefficients of the polynomials (5) and (7) for those materials whose conductivity changes with density. Table 3 shows maximum, minimum, standard deviation and two extreme fractiles (1% and 99%) for the rest of materials in table 1.
Figure 3 Section of a flat plate solar collector In this kind of solar collector, an absorber plate with high solar absorptance and low emittance absorbs solar radiation and transfers the energy to a working fluid flowing through the tubes. In order to reduce the heat losses from the plate to the ambient, the plate is put into a weatherproof casing with one or two frontal glass covers and insulation behind and around the plate. Insulation normally consists of a layer of fibreglass, mineral fibre or polyester fibre. The mathematical model of the collector requires around 20 input parameters to determine the efficiency curve. One of these parameters is the conductivity of the back insulation, in this case a mineral fibre mat 55 cm. thick, with nominal density 70 kg/m3. From table 2, the conductivity of this material at 10ºC is:
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Table 2 Coefficients a,b,c,d,e,h for materials whose conductivity depends on density, and minimum and maximum density of available data (declared conditions I(a)). Results in W/m·K a
where fT is the temperature conversion factor, whose value depends on the kind of insulation and its declared conductivity. From data in table A.1 of (ISO 10456, 1999), fT will be approached by the following normal distribution: fT = N [0.0042, 0.000392] K-1
Equation (8) tells us that, although the exact value of the declared conductivity of the back insulation of the tested collector is unknown, we can ensure that it will lie within [0.0289, 0.0383] W/m·K with a 99.7% probability. The operating temperature of the plate varies in a wide range, from near ambient temperature during nightime to more that 100ºC during stagnation periods. Because of this reason, the temperaturedependency of the thermal conductivity was included in the model. Accordingly to (ISO 10456, 1999), conductivity can be converted from a reference temperature (Tref) to any other temperature (T) by using this expression:
ξfT , kref
This means that the declared conductivity of the back insulation can be modelled by the following normal probability distribution:
k (T ) = k (Tref ) ⋅ exp ( fT (T − Tref ) )
σ = 0.001569 [W·m-1 ·K -1 ]
k10ºC ,dry = N [0.0336, 0.001569] W/m·K
1 ln ( αx + β ) fT
kref fT tinsul
β = exp ( fT (Tmp − Tref ) ) , ⎛ T − Tref exp ⎜ amb ⎜ T −T ref ⎝ mp
⎞ ⎟⎟ ⎠
In equation (9), T stands for the average temperature of the material. Integrating equation (14): Tinsul = Tref +
(16) Finally, equation (9) can be written as: k (T ) = N [0.00336, 0.001569] ⋅ exp ( N [0.0042, 0.000392](Tinsul − 10) )
Where Tinsul is calculated with equation (16). Other variables such us the transmittance of the glass cover, transport coefficients or plate emittance are treated in a similar way. All these uncertainties can be propagated through the model by applying the Monte Carlo method. A typical result is shown in figure 5 (Dominguez et al., 2008).
Because the Hottel-Whillier model is onedimensional, the temperature at the upper face of the back insulation layer will be set to the average temperature of the absorber plate (Tmp). Ambient temperature (Tamb) will be imposed at the bottom face of the insulation, figure 4.
Figure 4 Insulation thermal model The steady temperature field in the insulation layer is given by the Fourier law: ∇ ( k ∇T ) = 0
subject to the following boundary conditions: T(x=0) = Tmp
T(x=tinsul) = Tamb
Where tinsul is the thickness of the insulation layer. The problem defined by equations (9) and (11) to (13) has the following analytical solution
Figure 5 Measured and calculated efficiency curves with uncertainty bands Model and experiment compare reasonably well, although the model under predicts the heat losses (slope of the curves shown in figure 5) by 5.75% on average. A sensitivity analysis (Saltelli et al., 2004) identifies what input factors dominate the uncertainty in the heat losses. The slope mainly depends on: 1. Insulation conductivity 2. Plate emittance 3. Natural convection in the air-gap 4. Temperature conversion factor fT
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Four of these factors concern to input factors, not to the model itself. The differences between model and experiment could be explained if the true values of conductivity and/or plate emittance were slightly higher, and/or if their probability distributions were non-symmetrical. These results are helpful in pointing out future experimental research.
CONCLUSION The lack of information on the uncertainty in input factors is one of the most important difficulties that users find when trying to undertake a stochastic simulation. In this paper, we provide results that give a general estimation of the uncertainty that affects to the thermal conductivity of 18 common insulation materials. Reported uncertainties were extracted from an extensive data set that comprise products from different European manufacturers. Reported uncertainties could be further reduced by analyzing products from specific manufacturers. More research is encouraged to quantify the variability of the input data required by thermal systems simulation programs.
REFERENCES AHSRAE, 2005. Fundamentals Handbook 2005 Anderson B.R., Kosmina L., Panzhauser E., Lechleitner J., Achtziger J., Sandberg P.I., Johnsson B., Pompeo C., Frank T., Mühlebach H., Torroja B., 1999. Analysis, selection and statistical treatment of thermal properties of building materials for the preparation of harmonised design values – Final Report of the Thermal Values Group. BRE Scottish Laboratory, for Directorate General DG XII of the European Commission, Contract SMT4CT96-2050, March 1999 CIBSE, 2006. Environmental design, CIBSE Guide A. The Chartered Institution of Building Services Engineers, London. ISBN: 978-1903287-66-8 Clarke J.A., Yaneske P.P., Pinney A.A., 1990. The Harmonisation of Thermal Properties of Building Materials. Building Research Establishment (BRE), available at access February 2009 CTE, 2007. Código Técnico de la Edificación, available at , access February 2009 (in Spanish) De Wit M.S. 2001. Uncertainty in Predictions of Thermal Comfort in Buildings. Ph.D. Thesis, University of Delft, 2001 Domínguez-Muñoz F., Cejudo-López J.M., CarrilloAndrés A., 2008. Validación experimental del modelo de Hottel-Whillier de captador plano de
tubos paralelos. XIV Congreso Ibérico y IX Congreso Iberoamericano de Energía Solar. Vigo, España. June 2008. ISBN 978-84-6124470-6 (in Spanish) Duffie J.A., Beckman W.A., 2006. Solar Engineering of Thermal Processes. Third Edition, John Wiley and Sons. ISBN 978-0-471-69867-8 EN 12524, 2000. Building Materials and Products Hygrothermal Properties - Tabulated Design Values EN 12939, 2001. Thermal performance of building materials and products - Determination of thermal resistance by means of guarded hot plate and heat flow meter methods - Thick products of high and medium thermal resistance EN 1745, 2002. Masonry and masonry products. Methods for determining design thermal values ISO 10456, 2001. Building materials and products Procedures for determining declared and design thermal values Koo J., 1999. Development of a flat-plate solar collector design program. Master Thesis, Solar Energy Laboratory (SEL), University of Wisconsin-Madison, 1999 Lomas K.J., Eppel H., 1992. Sensitivity analysis techniques for building thermal simulation programs. Energy and Buildings, 19(1992) 2144 MacDonald I.A., 2001. Quantifying the effects of uncertainty in building simulation. Ph.D. Thesis, University of Strathclyde, July 2002 NIST 2006, NIST/SEMATECH e-Handbook of Statistical Methods, see (access February 2009) Palomo del Barrio E., Guyon G., 2003. Using parameters space analysis techniques for diagnostic purposes in the framework of empirical model validation – Theory, applications and computer implementation. A Report of Task 22, Subtask A. Building Energy Analysis Tools. IEA, International Energy Agency, Solar Heating and Cooling Programme Press W.H. et al., 1992. Numerical Recipes in Fortran 77, volume 1. Cambridge University Press Saltelli A., Tarantola S., Campolongo F., Ratto M., 2004. Sensitivity analysis in practice. John Wiley & Sons. ISBN 0-470-87093-1 STATSOFT,2008. Statgraphics software. Strachan P., 1993. Model Validation using the PASSYS Test Cells. Building and Environment, Vol. 28, No. 2, pp. t53-165